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Hands-on Science (H-Sci) Project: Chemical Safety Database

Chemical Safety Data: Hydrochloric acid


Hazard: toxic Hazard: corrosive


Common synonyms

None.

Formula

HCl

Physical properties

Form: Colourless to light yellow fuming liquid when concentrated; colourless liquid when diluted
Stability: Stable, but reacts vigorously or violently with most metals, bases and many other chemicals.
Melting point: -25 C (concentrated)
Boiling point: 109 C (concentrated)
Water solubility: Miscible in all proportions
Specific gravity: 1.19 (concentrated), close to 1 (dilute)

Principal hazards

Contact with the eyes or skin can cause serious permanent damage
Concentrated solutions of this acid are extremely corrosive; very dilute solutions are mildly corrosive.
Toxic by inhalation - the concentrated solution releases dangerous quantities of hydrogen chloride vapour

Safe handling

Always wear safety glasses. Do not allow the acid or a solution of it to come into contact with your skin. Wear gloves if handling the concentrated acid. The concentrated acid must always be used in an area equipped with good ventilation, never in the open laboratory.

Emergency

Eye contact: Immediately flush the eye with plenty of water. Continue for at least ten minutes and call for immediate medical help.
Skin contact: Wash off with plenty of water. Remove any contaminated clothing. If the skin reddens or appears damaged, call for medical aid.
If swallowed: Drink plenty of water and call for immediate medical help.

Disposal

Small amounts of dilute hydrochloric acid can be flushed down a sink with a large quantity of water, unless local rules prohibit this. Larger amounts should be neutralised before disposal. Concentrated acid should not be flushed down a sink.

Protective equipment

Always wear safety glasses when handling hydrochloric acid or its solutions. If you need gloves, use neoprene, butyl rubber, natural rubber, or nitrile. When handling the concentrated acid good ventilation is vital.

Further information

Hydrochloric acid
Chemicals in the HSci database
More extensive safety data

Link to the Oxford HSci web site
Oxford, December 31, 2003