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  Rotational Raman Spectroscopy
Interpreting the Spectrum page 2 of 2
   
Practical Navigator
Introduction
The Raman Effect
Experimental Techniques
1. Rotational Raman Spectroscopy
Interpreting the Spectrum
Effect of Bond Length
Centrifugal Distortion
Intensities of Spectral Lines
Nuclear Spin Statistics
2. Real Diatomic Molecules
Temperature
Spectrum of Nitrogen
Isotopic Substitution
Nuclear Spin Statistics
Predict the Spectrum of Oxygen
  You can click on the J+2 or J-2 buttons to show the transitions that lead to the Stokes and Anti Stokes transitions respectively.

Q1.1 What is the energy of the laser in wavenumber units?
Q1.2 What is this energy in Joules?
Q1.3 Calculate the moment of inertia for .
Q1.4 Write down the equation for the rotational constant B.
Q1.5 Calculate the rotational constant, B, for this molecule.
Q1.6 What is the equation for the rotational energy level of a rigid rotor?
Q1.7Calculate the energy in wavenumber units for the first 4 energy levels
Q1.8 Calculate the position of the first three Stokes and Anti-Stokes lines both in wavenumbers, measured from the exciting line, and in absolute wavelength.


Clicking on a particular spectral line shows which rotational energy levels are involved in that transition. Click on the first three lines and check if your answers are correct. If not check the units carefully. To remove the information box, click anywhere inside the spectra window.
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