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  Rotational Raman Spectroscopy
Introduction page 3 of 3
   
Practical Navigator
Introduction
The Raman Effect
Experimental Techniques
1. Rotational Raman Spectroscopy
Interpreting the Spectrum
Effect of Bond Length
Centrifugal Distortion
Intensities of Spectral Lines
Nuclear Spin Statistics
2. Real Diatomic Molecules
Temperature
Spectrum of Nitrogen
Isotopic Substitution
Nuclear Spin Statistics
Predict the Spectrum of Oxygen
  Lord Rayleigh showed in 1871 that the intensity of the scattered light is related to the wavelength of the exciting radiation by the equation:

I       (2)

In addition, photons may be detected at certain discrete frequencies above and below that of the incident beam; it is emission at these energies which is referred to as Raman Scattering.

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